NITRIC ACID

Indroduction

Nitric acid (HNO₃) is a highly corrosive and strong mineral acid with a wide range of applications in various industries. It is an important chemical compound with distinct properties and uses. Here's an overview of nitric acid:

CAS No.7697-37-2
Chemical Formula HNO3
Mol. Wt.63

Standard Specification

Total Acidity A HNO3

59.0 %w/w

 Nitrous Acid As HNO2100 ppm
 Chloride As Cl20 ppm
 Sulphate as H2SO4 20 ppm
Residue on Ignition 250 ppm
Flouride as F100.00 max
Ca and Mg50.00 max
 Heavy Metals as Pv (Lead)10.00 max
 Arsenic as F1 max
 ColourWater White

Chemical Properties

Nitric acid is a strong monoprotic acid, meaning it can donate a single proton (H⁺ ion) per molecule. Its chemical structure consists of one nitrogen atom, three oxygen atoms, and a hydrogen atom. When dissolved in water, it dissociates into hydrogen ions (H⁺) and nitrate ions (NO₃⁻).

Physical Properties:

DensityIts density is approximately 1.42 g/cm³.
Boiling PointNitric acid has a boiling point of around 83 °C (181 °F).
State

Nitric acid
is a colorless to yellowish liquid with a pungent and acrid odor.

Production

Nitric acid is commonly produced through the Ostwald process, which involves several steps:

Ammonia Oxidation

Ammonia
(NH₃) is oxidized with air in the presence of a catalyst (platinum or rhodium
gauze) to form nitrogen dioxide (NO₂) gas and water vapor.

Absorption

Nitrogen dioxide gas is then dissolved in water to form nitric acid and nitrogen monoxide (NO) through a series of chemical reactions.

Nitrogen
Monoxide Oxidation
Nitrogen
monoxide (NO) is further oxidized with oxygen to form nitrogen dioxide (NO₂),
which is then recycled back into the absorption step.

Uses

Nitric acid
has several important applications across industries:

Fertilizer
Production

It’s
a key component in the production of ammonium nitrate and other nitrogen-based
fertilizers.
Explosives
Nitric
acid is used in the manufacture of explosives like nitroglycerin and TNT.
Oxidizing Agent
 It serves as a strong oxidizing agent in various chemical processes and
laboratory procedures.
Metallurgy
Nitric
acid is used for etching and passivating stainless steel and other metals.
Dye
and Pigment Production

It’s used in
the production of dyes, pigments, and inks.

Pharmaceuticals
Nitric
acid is used in the synthesis of pharmaceutical intermediates and other
compounds.
Electronics
Industry
It’s
used for cleaning and etching semiconductor materials and electronic
components.
Rocket  Fuel

Nitric acid
is used as an oxidizer in certain liquid rocket propellants.

Safety Considerations

Nitric acid
is highly corrosive and poses significant health and safety risks. Direct
contact with skin, eyes, or mucous membranes can cause severe burns. Inhalation
of its vapors can lead to respiratory irritation and other health issues. It’s
important to handle nitric acid with proper protective equipment, ventilation,
and safety precautions.

 

In conclusion, nitric acid is a versatile and powerful chemical with a wide range of applications in various industries. Its corrosive nature and potential hazards underscore the importance of proper handling and adherence to safety guidelines when working with this chemical.